Here, the Peltier effect manifests itself in the interaction of conduction electrons, slowed down or accelerated in the contact potential of the pn junction, with thermal oscillations of atoms in the semiconductor array. As a result, depending on the direction of movement of the electrons and, accordingly, the current, heating or cooling of the section of the semiconductor directly adjacent to the junction ( pn or np junction) occurs .
The Peltier effect underlies the operation of a thermoelectric module (TEM). A single element of TEM is a thermocouple, consisting of one conductor (branch) of p- type and one conductor of n- type. When several such thermocouples are connected in series, the heat ( Qc), absorbed on the contact type n - p , stands out on the contact type p - n ( Qh). A thermoelectric module is a collection of such thermocouples, usually interconnected sequentially in current and in parallel in heat flux. Thermocouples are placed between two ceramic plates. The branches are soldered to copper conductive pads (skins), which are attached to special heat-conducting ceramics, for example, from aluminum oxide. The number of thermocouples can vary widely - from several units to several hundred, which allows you to create TEM with a cooling capacity of from tenths of a watt to hundreds of watts. Among the TEM materials, bismuth telluride has the highest thermoelectric efficiency, in which special additives, for example, selenium and antimony, are added to obtain the required type and conductivity parameters. Traditionally, the side to which the wires are attached is hot, and it is depicted from below.